Product ID:BULLDOG PLASTIC ROOF CEMENT
MSDS Date:01/01/1990
FSC:5610
NIIN:00N011269
MSDS Number: BJJZB

PALMER ASPHALT COMPANY

196 WEST 5TH STREET
BAYONNE, NJ 07002
US

Emergency Phone: 201-339-0855

Info Phone: 201-339-0855

Cage: 86371

PALMER ASPHALT CO

58 BAYONNE, NJ 07002-1102 US

Cage: 86371

POSS.DO NOT CLEAN;RESIDUE DFCLT TO

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

THORO AFTER CONT,BEFORE BREAKS,MEALS,AFTER

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

VM&P NAPHTHA (LIGROINE)

CAS: 8032-32-4

RTECS: OI6180000

Fraction By Weight: <30%

OSHA PEL 300 PPM/400 STEL

ACGIH TLV: 300 PPM; 9192

PETROLEUM ASPHALT

CAS: 8052-42-4

RTECS: CI9905000

Fraction By Weight: <70%

OSHA PEL N/K

ACGIH TLV: 5 MG/M3 FUME

ASBESTOS FIBERS

CAS: 1332-21-4

RTECS: CI6475000

Fraction By Weight: <25%

OSHA PEL 0.2 FIBERS/CC

ACGIH TLV: 2 FIBERS/CC

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ANIM (IARC,1987).KNOWN HUM CARC

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

1985).KNOWN TO CAUSE CANCER (CAL PROP

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HIGH VAP CONC (>1000 PPM) MAY CAUSE
DEATH.PRLNG/RPTD SKIN CONT MAY LEAD TO DERM.ASPIR OF SM AMT INTO
LUNGS DURING INGEST MAY CAUSE MILD TO SEV PULM INJURY,POSS
DEATH.ASBESTOS FIBERS IN PROD ENCAPSULAT ED & NOT CONSIDERED HLTH
HAZ (MFR).LONGTERM INH OVEREXP TO UNENCAPSULATED
FIBERS:ASBESTOSIS,ASBESTOS AIRWAY (SEE SUPP)
Explanation of Carcinogenicity:ASBESTOS FIBERS:PROD FIBERS ENCAPSULATED
& NOT CONSIDERED A HLTH HAZARD (MFR).UNENCAPSULATED ASBESTOS
FIBERS:(SEE SUPP)
Effects of Overexposure:EYES:SEV IRRIT,REDNESS,TEARING,BLURRED
VISION.SKIN:PRLNG/RPTD CONT-MOD IRRIT,DEFAT,DERMAT;LOW ODOR DERMAL
TOX.INGEST:ASPIR HAZ-SM AMT IN LUNGS MAY CAUSE MILD TO SEV PULM
INJURY,POSS DEATH;LOW ODOR ORA L TOX.INH:VAP CAN CAUSE NOSE/THROAT
IRRIT,DIZZ,WEAK,FATG,NAUS,HDCH,ANESTHESIA,POSS
UNCON,ASPHYXIATION,OTHER CNS EFTS.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING CENTRAL
NERVOUS SYSTEM DISEASE,SKIN DISORDERS,OR CHRONIC RESPIRATORY
DISEASE SHOULD AVOID EXPOSURE TO THIS PRODUCT.

First Aid:EYES:FLUSH W/ LARGE AMTS OF WATER FOR AT LEAST 15 MIN.GET MED
ATTN.SKIN:REMOVE CONTAM CLTHG,WASH THORO W/ SOAP & WATER.IF
IRRIT/REDNESS DEVELOPS & PERSISTS,GET MED ATTN.INGEST:DO NOT INDUCE
VOMIT.TAKE IMMED TO HOSPITAL.GET MED ATTN IMMED.MD NOTE:GASTRIC
LAVAGE IAW PROCEDURE FOR PETRO PROD.INH:REMOVE TO FRESH AIR.DFCLT
BRTHG-GIVE O*2.BRTHG STOPPED-GIVE ARTF RESP.KEEP WARM,QUIET.GET
MEDICAL ATTN.

Flash Point Method:TCC
Flash Point:100F,38C (MIN)
Lower Limits:7.0%
Upper Limits:0.9%
Extinguishing Media:DRY CHEMICAL & CO*2;UNIVERSAL TYPE FOAM,WATER FOG
EFFECTIVE,BUT MAY CAUSE FROTHING.DO NOT USE WATER (PETRO CMPDS
FLOAT).
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .DO NOT USE WATER (PETRO-BASED CMPDS CAN FLOAT
ON H*2O).UNIVERSAL FOAM,H*2O MAY CAUSE FROTHING.
Unusual Fire/Explosion Hazard:DO NOT
PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRIND,EXPOSE CONTRS TO
HEAT,FLAME,SPARKS,IGNIT SOURCE.THEY MAY EXPLO,CAUSE
INJURY/DEATH.AUTOIGNIT TEMP:(SUPP DATA)

Spill Release Procedures:SHUT OFF/ELIM IGNIT SOURCES.KEEP PERS
AWAY.RECOVER FREE PROD.ADD SAND,EARTH,OTHER ABSORB.AVOID SKIN
CONT/BRTHG VAP.VENT CONFINED SPACES;OPEN WINDOWS/DOORS.DIKE/IMPOUND
TO KEEP OUT OF SEWERS,WATERCOURS ES.IF IN SEWER,WATERWAY,LG LAND
AREA:ADVISE AUTH.
Neutralizing Agent:N/K

Handling and Storage Precautions:KEEP CONTRS CLSD TIGHT.KEEP CONTRS
COOL,DRY,AWAY FROM IGNIT SOURCES.USE W/ ADEQ VENT.MATERIAL REQUIRES
ELECTRICAL GROUNDING DURING TRANSFER.COMBUST.
Other Precautions:INSTALL ELEC EQUIP IN HNDLG/STOR AREA PER NFPA
REQUIREMENTS.MINIMIZE VAP/LIQ/MIST/FUME EXPOSURE.EMPTY CONTRS
RETAIN RESIDUE (LIQ/VAP) & CAN BE DANGEROUS.DO NOT
PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,G RIND,EXPOSE TO
HEAT,FLAME,SPK,(INGRED 5)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL & GENERAL VENT NEC TO KEEP AIR CONC BELOW LEVEL OF
CONCERN .USE EXPLO-PROOF EQUIP.NO SMKNG/OPEN LIGHTS.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SPLASH GOGGLES AND FACESHIELD.
Other Protective Equipment:USE CHEMICAL-RESISTANT APRON AND OTHER
IMPERVIOUS CLOTHING TO AVOID SKIN CONTACT.
Work Hygienic Practices:MINIMIZE BRTHG VAP/MIST.AVOID PRLNG/RPTD SKIN
CONT.REMOVE CONTAM CLTHG;LAUNDER/DRY CLEAN BEFORE REUSE.WASH SKIN
(ING 7)
Supplemental Safety and Health
VP:APPROX 5 MMHG @ 70F,21C (EST).VAP DENS:APPROX 5.0
(AIR=1).SOLUBILITY:<0.1% @ 1 ATM,77F,25C (SOLV).EXPLO
HAZ:400F,204C.HAZ DECOMP PROD:CO*2,CO,NITROGEN OXIDES;TOX
MATLS.ENTRY RTE:INH/SKIN/INGEST (FP N).HLTH HAZ:DISEASE,LUNG
CARCINOMA,PLEURAL/PERITONEAL MESOTHELIOMA.EXPLAN OF CARC:SUFF EVID
FOR CARC IN HUM & (ING 4)

Boiling Pt:B.P. Text:380F,193C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:SEE SUPP
Vapor Density:SEE SUPP
Spec Gravity:>1.00 (WATER=1)
pH:NEUT
Evaporation Rate & Reference:N/K
Solubility in Water:SEE SUPP DATA
Appearance and Odor:BLACK,THICK CONSISTENCY ASPHALT CEMENT WITH A
SLIGHT PETROLEUM HYDROCARBON ODOR
Percent Volatiles by Volume:<30

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS LIKE:LIQUID CHLORINE,CONCENTRATED OXYGEN,SODIUM OR
CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:KEEP FROM HEAT,SPARKS,OPEN FLAME.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,AND
NITROGEN OXIDES;TOXIC MATERIALS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.